1993•Journal of the Indian Society of Soil ScienceOpen access

Chemistry and Availability of Phosphate from Rock Phosphate Treated with Oxalic Acid in Calcareous Soil

C. P. Singh, D. S. Ruhal

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Abstract

Oxalic acid was used to solubilize low grade rock phosphate through wet blending in various ratios on dry weight basis and availability of P from blended rock phosphate was compared with superphosphate in calcareous soil up to 84 days. Available P increased in soil with increasing levels of oxalic acid with rock phosphate. At lower oxalic acid concentration, availability of P increased up to a certain level and thereafter decreased drastically due to formation of Ca-P in the system while at higher levels Ca-P decreased gradually. Oxalic acid: rock phosphate ratio of 1:2 wasfound comparable with SSP in respect to availability of P in soil.

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Oxalic acid was used to solubilize low grade rock phosphate through wet blending in various ratios on dry weight basis and availability of P from blended rock phosphate was compared with superphosphate in calcareous soil up to 84 days. Available P increased in soil with increasing levels of oxalic acid with rock phosphate. At lower oxalic acid concentration, availability of P increased up to a certain level and thereafter decreased drastically due to formation of Ca-P in the system while at higher levels Ca-P decreased gradually. Oxalic acid: rock phosphate ratio of 1:2 wasfound comparable with SSP in respect to availability of P in soil.

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Available abstract

Oxalic acid was used to solubilize low grade rock phosphate through wet blending in various ratios on dry weight basis and availability of P from blended rock phosphate was compared with superphosphate in calcareous soil up to 84 days. Available P increased in soil with increasing levels of oxalic acid with rock phosphate. At lower oxalic acid concentration, availability of P increased up to a certain level and thereafter decreased drastically due to formation of Ca-P in the system while at higher levels Ca-P decreased gradually. Oxalic acid: rock phosphate ratio of 1:2 wasfound comparable with SSP in respect to availability of P in soil.

Key concepts: Oxalic acid, Phosphorite, Calcareous, Phosphate, Chemistry, Calcareous soils, Nuclear chemistry, Mineralogy

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