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HIGH RESOLUTION RAMAN SPECTRUM OF METHYL FLUORIDE-$d_{3}$

Fletcher, W. H., Stephen J. Daunt

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Abstract

The Raman spectra of the $\\nu_{1}$ and $\\nu_{4}$ fundamentals of methyl fluoride $d_{3}$ have been observed with resolution ranging from $0.06\\;cm^{-1}$ to $0.40\\;cm^{-1}$. The Q branches of $2\\nu_{2}$ and $2\\nu_{5}$ which fall in the $\\nu_{4}$ region, have also been examined at $0.06\\;cm^{-1}$ resolution. The analysis of the observed spectra and the resulting molecular constants will be discussed.

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What this paper is about

The Raman spectra of the $\\nu_{1}$ and $\\nu_{4}$ fundamentals of methyl fluoride $d_{3}$ have been observed with resolution ranging from $0.06\\;cm^{-1}$ to $0.40\\;cm^{-1}$. The Q branches of $2\\nu_{2}$ and $2\\nu_{5}$ which fall in the $\\nu_{4}$ region, have also been examined at $0.06\\;cm^{-1}$ resolution. The analysis of the observed spectra and the resulting molecular constants will be discussed.

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Available abstract

The Raman spectra of the $\\nu_{1}$ and $\\nu_{4}$ fundamentals of methyl fluoride $d_{3}$ have been observed with resolution ranging from $0.06\\;cm^{-1}$ to $0.40\\;cm^{-1}$. The Q branches of $2\\nu_{2}$ and $2\\nu_{5}$ which fall in the $\\nu_{4}$ region, have also been examined at $0.06\\;cm^{-1}$ resolution. The analysis of the observed spectra and the resulting molecular constants will be discussed.

Key concepts: Raman spectroscopy, Fluoride, Materials science, Physics, Optics, Chemistry, Inorganic chemistry

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