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THE MICROWAVE SPECTRUM, STRUCTURE AND DIPOLE MOMENT OF 2,3 DICARBAHEXABORANE(6).

Poynter, L. R, Robert A. Beaudet

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Abstract

The microwave spectra of all mono-substituted boron isotopic species and three doubly substituted boron species have been observed and analyzed for 2,3 dicarbahexaborane (6). The analysis of the rotational spectrum shows that this molecule has the structural form of a tetragonal bipyramid. The carbon atoms are adjacent and are both located in the trapezoidal base. No hydrogen bonding occurs. The molecule is very nearly a spherical rotor. The dipole moment, 1.50 Debyes, is oriented along the planar symmetry axis.

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What this paper is about

The microwave spectra of all mono-substituted boron isotopic species and three doubly substituted boron species have been observed and analyzed for 2,3 dicarbahexaborane (6). The analysis of the rotational spectrum shows that this molecule has the structural form of a tetragonal bipyramid. The carbon atoms are adjacent and are both located in the trapezoidal base. No hydrogen bonding occurs. The molecule is very nearly a spherical rotor. The dipole moment, 1.50 Debyes, is oriented along the planar symmetry axis.

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Available abstract

The microwave spectra of all mono-substituted boron isotopic species and three doubly substituted boron species have been observed and analyzed for 2,3 dicarbahexaborane (6). The analysis of the rotational spectrum shows that this molecule has the structural form of a tetragonal bipyramid. The carbon atoms are adjacent and are both located in the trapezoidal base. No hydrogen bonding occurs. The molecule is very nearly a spherical rotor. The dipole moment, 1.50 Debyes, is oriented along the planar symmetry axis.

Key concepts: Moment (physics), Dipole, Microwave, Spectrum (functional analysis), Physics, Nuclear magnetic resonance, Quantum mechanics

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THE MICROWAVE SPECTRUM, STRUCTURE AND DIPOLE MOMENT OF 2,3 DICARBAHEXABORANE(6). — Research Paper | ScholarLens