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ON RADICALS PRODUCED BY LOW-TEMPERATURE TOLUENE RADIOLYSIS

N.Ya. Buben, V. A. Tolkachev, I.I. Chkheidze

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Abstract

Spectra of electron paramagnetic resonance radicals formed by fast electron irradiation of frozen C/sub 6/H/sub 5/CH/sub 3/ and ra for phenyl, benzyl, and cyclohexadiene radicals. It is shown that hydrogen atoms initiallw, broken off of the CH/sub 3/ group and phenyl ring react differently with the admixtures and form cyclohexadiene radicals while the first radicals having higher kinetic energy are spent during the second process in which the second hydrogen atom breaks off from the toluene molecule. (R.V.J.)

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Spectra of electron paramagnetic resonance radicals formed by fast electron irradiation of frozen C/sub 6/H/sub 5/CH/sub 3/ and ra for phenyl, benzyl, and cyclohexadiene radicals. It is shown that hydrogen atoms initiallw, broken off of the CH/sub 3/ group and phenyl ring react differently with the admixtures and form cyclohexadiene radicals while the first radicals having higher kinetic energy are spent during the second process in which the second hydrogen atom breaks off from the toluene molecule. (R.V.J.)

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Available abstract

Spectra of electron paramagnetic resonance radicals formed by fast electron irradiation of frozen C/sub 6/H/sub 5/CH/sub 3/ and ra for phenyl, benzyl, and cyclohexadiene radicals. It is shown that hydrogen atoms initiallw, broken off of the CH/sub 3/ group and phenyl ring react differently with the admixtures and form cyclohexadiene radicals while the first radicals having higher kinetic energy are spent during the second process in which the second hydrogen atom breaks off from the toluene molecule. (R.V.J.)

Key concepts: Radical, Radiolysis, Toluene, Chemistry, Electron paramagnetic resonance, Photochemistry, Hydrogen atom, Hydrogen

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