2011Advanced materials researchOpen access

MnxZn1-xO Crystal Synthesized by Hydrothermal Method

Wen Li Zheng, Su Xin Wang, Zhi Wen Li

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Abstract

MnxZn1-XO Crystal was synthesized by hydrothermal method in this work.The experimental parameters for hydrothermal synyhesis were:Mineralizer concentration 3mol•L-1KOH, the fill factor 35%, temperature 430°C, Zn(OH)2 doped with MnO2 as precursor, and the reaction time 24 hours. The Mn concentration in crystal was determined by X-ray EDS. The atomic percentage of Mn in crystal increases as the concentration of MnO2 in precursor increased. The maximum atomic percentage for Mn is over 2%. The morphology shows characteristics of hexagonal prism of pure ZnO crystal. The exposed faces are hexagonal faces m{10 0}, hexagonal cone faces p{10 1}, negative polar faces {000 }and positive polar faces{0001}. The diameters of the crystals are 50-200μm,the heights are 20-100μm.

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What this paper is about

MnxZn1-XO Crystal was synthesized by hydrothermal method in this work.The experimental parameters for hydrothermal synyhesis were:Mineralizer concentration 3mol•L-1KOH, the fill factor 35%, temperature 430°C, Zn(OH)2 doped with MnO2 as precursor, and the reaction time 24 hours. The Mn concentration in crystal was determined by X-ray EDS. The atomic percentage of Mn in crystal increases as the concentration of MnO2 in precursor increased. The maximum atomic percentage for Mn is over 2%. The morphology shows characteristics of hexagonal prism of pure ZnO crystal. The exposed faces are hexagonal faces m{10 0}, hexagonal cone faces p{10 1}, negative polar faces {000 }and positive polar faces{0001}. The diameters of the crystals are 50-200μm,the heights are 20-100μm.

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Available abstract

MnxZn1-XO Crystal was synthesized by hydrothermal method in this work.The experimental parameters for hydrothermal synyhesis were:Mineralizer concentration 3mol•L-1KOH, the fill factor 35%, temperature 430°C, Zn(OH)2 doped with MnO2 as precursor, and the reaction time 24 hours. The Mn concentration in crystal was determined by X-ray EDS. The atomic percentage of Mn in crystal increases as the concentration of MnO2 in precursor increased. The maximum atomic percentage for Mn is over 2%. The morphology shows characteristics of hexagonal prism of pure ZnO crystal. The exposed faces are hexagonal faces m{10 0}, hexagonal cone faces p{10 1}, negative polar faces {000 }and positive polar faces{0001}. The diameters of the crystals are 50-200μm,the heights are 20-100μm.

Key concepts: Hexagonal prism, Hydrothermal circulation, Crystal (programming language), Hexagonal crystal system, Materials science, Crystallography, Hydrothermal synthesis, Crystal structure

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