Genesis of volatile components at Saturn’s regular satellites. Origin of Titan’s atmosphere

Jupiter’s and Saturn’s regular satellites, which posses much ice, are currently thought to have been formed during the early evolution of the Solar System in circumplanetary protosatellite disks. Two of Saturn’s regular satellites—Titan and Enceladus—were experimentally proved to contain, along with water, other volatile components: molecular nitrogen, and methane (which are the major components of Titan’s atmosphere) and various nitrogen and carbon compounds in water plumes of Enceladus. The protomaterial of these rocky–icy satellites was formed in the outer regions of the gas–dust circumsolar nebula, and its closest analogue currently accessible to study is cometary material. The paper presents a review of experimental data on the chemical and isotopic composition of cometary material as possible sources of volatile components on Titan and Enceladus and model evaluations of temperatures in the circumsolar gas–dust protoplanetary disk and Jupiter’s and Saturn’s protosatellite disks during various evolutionary episodes of the solar system. The P – T parameters of the origin of the protomaterial of Jupiter’s and Saturn’s regular satellites were proved to have been remarkably different, and hence, the material of Europa, a Jupiter’s regular satellite, cannot contain any volatile components other than water, in contrast to Titan and Enceladus. This conclusion is supported by experimental data. Cometary material is likely genetically related to the material of Saturn’s regular satellites Titan and Enceladus. The paper presents results of thermodynamic simulation of the evolution of the chemical and phase composition of Saturn’s satellites and suggests a model for the origin of Titan’s nitrogen–methane atmosphere.