2010•Eurasian Chemico-Technological JournalOpen access

Nanodispersed Ni-catalysts with Additives in Partial Oxidation of Methane

Н. А. Закарина, G.V. Akulova, Ju.M. Arinkin

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Abstract

Catalytic activity of Ni-Zn-surface-skeletal catalysts modi ed by Rh, Au, Ti, Mo and W in the reaction of methane partial oxidation has been studied. In uence of catalysts of conditions preparation on its catalytic activity was researched. It was shown that introduction of additives in Ni-Zn catalysts promote to increasing of activity in the process of methane partial oxidation to synthesis-gas and thermostability of skeletal Nicatalysts thanks to the change of its faseous composition and the predominance of reduced form of Ni in catalysts structure.

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Catalytic activity of Ni-Zn-surface-skeletal catalysts modi ed by Rh, Au, Ti, Mo and W in the reaction of methane partial oxidation has been studied. In uence of catalysts of conditions preparation on its catalytic activity was researched. It was shown that introduction of additives in Ni-Zn catalysts promote to increasing of activity in the process of methane partial oxidation to synthesis-gas and thermostability of skeletal Nicatalysts thanks to the change of its faseous composition and the predominance of reduced form of Ni in catalysts structure.

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Available abstract

Catalytic activity of Ni-Zn-surface-skeletal catalysts modi ed by Rh, Au, Ti, Mo and W in the reaction of methane partial oxidation has been studied. In uence of catalysts of conditions preparation on its catalytic activity was researched. It was shown that introduction of additives in Ni-Zn catalysts promote to increasing of activity in the process of methane partial oxidation to synthesis-gas and thermostability of skeletal Nicatalysts thanks to the change of its faseous composition and the predominance of reduced form of Ni in catalysts structure.

Key concepts: Catalysis, Partial oxidation, Methane, Thermostability, Chemistry, Inorganic chemistry, Anaerobic oxidation of methane, Materials science

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