2013Physical Review LettersOpen access

Theory of a Competitive Spin Liquid State for Weak Mott Insulators on the Triangular Lattice

Ryan V. Mishmash, James R. Garrison, Samuel Bieri, Cenke Xu

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Abstract

We propose a novel quantum spin liquid state that can explain many of the intriguing experimental properties of the low-temperature phase of the organic spin liquid candidate materials $\ensuremath{\kappa}\mathrm{\text{\ensuremath{-}}}(\mathrm{BEDT}\mathrm{\text{\ensuremath{-}}}\mathrm{TTF}{)}_{2}{\mathrm{Cu}}_{2}(\mathrm{CN}{)}_{3}$ and ${\mathrm{EtMe}}_{3}\mathrm{Sb}[\mathrm{Pd}(\mathrm{dmit}{)}_{2}{]}_{2}$. This state of paired fermionic spinons preserves all symmetries of the system, and it has a gapless excitation spectrum with quadratic bands that touch at momentum $\stackrel{\ensuremath{\rightarrow}}{k}=0$. This quadratic band touching is protected by symmetries. Using variational Monte Carlo techniques, we show that this state has highly competitive energy in the triangular lattice Heisenberg model supplemented with a realistically large ring-exchange term.

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We propose a novel quantum spin liquid state that can explain many of the intriguing experimental properties of the low-temperature phase of the organic spin liquid candidate materials $\ensuremath{\kappa}\mathrm{\text{\ensuremath{-}}}(\mathrm{BEDT}\mathrm{\text{\ensuremath{-}}}\mathrm{TTF}{)}_{2}{\mathrm{Cu}}_{2}(\mathrm{CN}{)}_{3}$ and ${\mathrm{EtMe}}_{3}\mathrm{Sb}[\mathrm{Pd}(\mathrm{dmit}{)}_{2}{]}_{2}$. This state of paired fermionic spinons preserves all symmetries of the system, and it has a gapless excitation spectrum with quadratic bands that touch at momentum $\stackrel{\ensuremath{\rightarrow}}{k}=0$. This quadratic band touching is protected by symmetries. Using variational Monte Carlo techniques, we show that this state has highly competitive energy in the triangular lattice Heisenberg model supplemented with a realistically large ring-exchange term.

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Available abstract

We propose a novel quantum spin liquid state that can explain many of the intriguing experimental properties of the low-temperature phase of the organic spin liquid candidate materials $\ensuremath{\kappa}\mathrm{\text{\ensuremath{-}}}(\mathrm{BEDT}\mathrm{\text{\ensuremath{-}}}\mathrm{TTF}{)}_{2}{\mathrm{Cu}}_{2}(\mathrm{CN}{)}_{3}$ and ${\mathrm{EtMe}}_{3}\mathrm{Sb}[\mathrm{Pd}(\mathrm{dmit}{)}_{2}{]}_{2}$. This state of paired fermionic spinons preserves all symmetries of the system, and it has a gapless excitation spectrum with quadratic bands that touch at momentum $\stackrel{\ensuremath{\rightarrow}}{k}=0$. This quadratic band touching is protected by symmetries. Using variational Monte Carlo techniques, we show that this state has highly competitive energy in the triangular lattice Heisenberg model supplemented with a realistically large ring-exchange term.

Key concepts: Spinon, Mott insulator, Quantum spin liquid, Variational Monte Carlo, Hexagonal lattice, Physics, Condensed matter physics, Gapless playback

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