2-[4-Benzyl-5-(2-furyl)-4H-1,2,4-triazol-3-ylsulfanyl]acetamide
Muhammad Zareef, Rashid Iqbal, Mohammad Arfan, Masood Parvez
Abstract
Muhammad Zareef, Rashid Iqbal, Mohammad Arfan, Masood Parvez
Abstract
In the title compound, C(15)H(14)N(4)O(2)S, the phenyl ring is inclined at 70.25 (6)° with respect to the approximately planar fur-yl-triazolsulfan-yl-acetamide unit. In the crystal structure, mol-ecules related by inversion centers form dimers via inter-molecular N-H⋯O hydrogen bonds between acetamide groups, resulting in eight-membered rings with an R(2) (2)(8) motif. In addition, the other H atom of the acetamide group is involved in an inter-molecular hydrogen bond with an N atom of the triazole ring, resulting in chains extended along the c axis. The overall effect is the formation of a hydrogen-bonded two-dimensional framework perpendicular to the a axis.
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In the title compound, C(15)H(14)N(4)O(2)S, the phenyl ring is inclined at 70.25 (6)° with respect to the approximately planar fur-yl-triazolsulfan-yl-acetamide unit. In the crystal structure, mol-ecules related by inversion centers form dimers via inter-molecular N-H⋯O hydrogen bonds between acetamide groups, resulting in eight-membered rings with an R(2) (2)(8) motif. In addition, the other H atom of the acetamide group is involved in an inter-molecular hydrogen bond with an N atom of the triazole ring, resulting in chains extended along the c axis. The overall effect is the formation of a hydrogen-bonded two-dimensional framework perpendicular to the a axis.
Key concepts: Acetamide, Triazole, Chemistry, Hydrogen bond, Ring (chemistry), Crystal structure, Crystallography, Stereochemistry