Phenol Adsorption on Nitrogen-Enriched Activated Carbon from Wood Fiberboard Waste

Nitrogen-enriched activated carbons were prepared from wood fiberboard waste using 50% potassium hydroxide solution. Activated carbons were obtained with an impregnation ratio (gram chemical agent/gram wood fiberboard waste) of 3 in 850°C activation temperature carbonized for 60 min. Nitrogen content in activated carbon was 1.33% by analysis. Effects of contact time, pH, adsorbent dosage level, and temperature on phenol adsorption capacity of activated carbons were investigated. Adsorption equilibrium was achieved within 100 min at the given phenol concentration of 250 mg/L. When 0.1 g of the carbon absorbent and 100 mL of phenol solution at 250 mg/L were used, maximum adsorption capacity of phenol on activated carbon can reach 207 mg/g. The kinetics of phenol adsorption followed nicely the pseudo-second-order rate expression. In the adsorption isotherm, the Langmuir model fit better than the Freundlich model in phenol adsorption. This study suggests that nitrogen-enriched activated carbon prepared from wood fiberboard waste can be used effectively for removal of phenol compounds from aqueous solutions.