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DETERMINATION OF ZIRCONIUM WITH N-BENZOYLPHENYLHYDROXYLAMINE

I.P. Alimarin, Yin Tse

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Abstract

A new method was developed for the quantitative precipitation of zirconium with N-benzoylphenylhydroxylamine. The influence of different mineral acids, tartaric acid, and hydrogen peroxide on the completeness of the zirconium precipitation with N-benzoylphenylhydroxylamine was studied. Precipitation of zirconium in the presence of other elements was investigated. It was shown that zirconium can be separated from iron, aluminum, chromium, titanium, niobium, and tantalum. The composition of zirconium benzoylphenylhydroxylaminate was determined; the precipitate separated from a strong acid solution corresponds to the formula Zr(BPHS)/sub 4/. (auth)

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What this paper is about

A new method was developed for the quantitative precipitation of zirconium with N-benzoylphenylhydroxylamine. The influence of different mineral acids, tartaric acid, and hydrogen peroxide on the completeness of the zirconium precipitation with N-benzoylphenylhydroxylamine was studied. Precipitation of zirconium in the presence of other elements was investigated. It was shown that zirconium can be separated from iron, aluminum, chromium, titanium, niobium, and tantalum. The composition of zirconium benzoylphenylhydroxylaminate was determined; the precipitate separated from a strong acid solution corresponds to the formula Zr(BPHS)/sub 4/. (auth)

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Available abstract

A new method was developed for the quantitative precipitation of zirconium with N-benzoylphenylhydroxylamine. The influence of different mineral acids, tartaric acid, and hydrogen peroxide on the completeness of the zirconium precipitation with N-benzoylphenylhydroxylamine was studied. Precipitation of zirconium in the presence of other elements was investigated. It was shown that zirconium can be separated from iron, aluminum, chromium, titanium, niobium, and tantalum. The composition of zirconium benzoylphenylhydroxylaminate was determined; the precipitate separated from a strong acid solution corresponds to the formula Zr(BPHS)/sub 4/. (auth)

Key concepts: Zirconium, Precipitation, Titanium, Niobium, Inorganic chemistry, Tantalum, Tartaric acid, Zirconium alloy

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