2015Achievements in the Life SciencesOpen access

Assessment of Organochlorine Pesticide Residues in Water, Sediments and Fish from Lake Tashk, Iran

Farshid Kafilzadeh

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Abstract

In this study, the levels of organochlorine (OC) pesticide residues in Lake Tashk have been investigated using water, sediment and fish (carp) samples as a case study to find out the extent of pesticide contamination and accumulation in the lake. Six OC pesticides namely DDT, DDE, lindane, endosulfan, heptachlor and chlordane were analyzed in four sites at four seasons. Water samples were processed using a liquid–liquid extraction technique and gas chromatograph equipped with electron capture detector (GC-ECD). Soxhlet extraction was used for fish and sediment samples followed by clean up and gas chromatograph. DDE was the predominant residue in all the samples analyzed, at the mean concentrations of 0.075 ppb, 8.750 ppb and 4.446 ppb in water, sediment and fish samples, respectively. The lowest levels of OC pesticides were related to heptachlor and chlordane which none of them were found in water samples. Gonban and Midstream sites had the highest and the lowest concentrations of OC pesticides, respectively.

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In this study, the levels of organochlorine (OC) pesticide residues in Lake Tashk have been investigated using water, sediment and fish (carp) samples as a case study to find out the extent of pesticide contamination and accumulation in the lake. Six OC pesticides namely DDT, DDE, lindane, endosulfan, heptachlor and chlordane were analyzed in four sites at four seasons. Water samples were processed using a liquid–liquid extraction technique and gas chromatograph equipped with electron capture detector (GC-ECD). Soxhlet extraction was used for fish and sediment samples followed by clean up and gas chromatograph. DDE was the predominant residue in all the samples analyzed, at the mean concentrations of 0.075 ppb, 8.750 ppb and 4.446 ppb in water, sediment and fish samples, respectively. The lowest levels of OC pesticides were related to heptachlor and chlordane which none of them were found in water samples. Gonban and Midstream sites had the highest and the lowest concentrations of OC pesticides, respectively.

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Available abstract

In this study, the levels of organochlorine (OC) pesticide residues in Lake Tashk have been investigated using water, sediment and fish (carp) samples as a case study to find out the extent of pesticide contamination and accumulation in the lake. Six OC pesticides namely DDT, DDE, lindane, endosulfan, heptachlor and chlordane were analyzed in four sites at four seasons. Water samples were processed using a liquid–liquid extraction technique and gas chromatograph equipped with electron capture detector (GC-ECD). Soxhlet extraction was used for fish and sediment samples followed by clean up and gas chromatograph. DDE was the predominant residue in all the samples analyzed, at the mean concentrations of 0.075 ppb, 8.750 ppb and 4.446 ppb in water, sediment and fish samples, respectively. The lowest levels of OC pesticides were related to heptachlor and chlordane which none of them were found in water samples. Gonban and Midstream sites had the highest and the lowest concentrations of OC pesticides, respectively.

Key concepts: Heptachlor, Chlordane, Environmental chemistry, Lindane, Electron capture detector, Pesticide, Sediment, Gas chromatography

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