The speciation of inorganic carbon in estuarine and interstitial waters

A calculation procedure to obtain pH, total alkalinity and concentration of inorganic carbon, based on the application of Gran functions, is described. An iterative program was used to optimise the electrode standard potential (E₀) and inorganic carbon concentration. Alkalinities higher than 15 mM were detected in interstitial waters from sediments collected in Cadiz Bay. A contribution of 20 % was associated with those acid-based species other than inorganic carbon. Speciation of inorganic carbon in estuarine waters was characterised using laboratory simulation techniques. Total carbonate and alkalinity, as well as inorganic carbon concentration, present conservative behaviour in the mixing process of waters having different salinities.