2013Unpublished venueRequires access

Relationship of parameters of the critical point of phase gas-liquid transition with boyle temperature

Ihtiyor H. Umirzakov

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Abstract

It is shown that for 21 real substances the relation of Boyle temperature to the product of critical temperature and critical compressibility factor with high precision is equal to number 9, predicted by the state equation of van der Waals. We proposed the ratio for finding the critical volume through the relation of Boyle temperature to critical pressure. We also suggest a formula for determining the critical volume through the critical temperature and parameters of straight line of single compressibility.

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What this paper is about

It is shown that for 21 real substances the relation of Boyle temperature to the product of critical temperature and critical compressibility factor with high precision is equal to number 9, predicted by the state equation of van der Waals. We proposed the ratio for finding the critical volume through the relation of Boyle temperature to critical pressure. We also suggest a formula for determining the critical volume through the critical temperature and parameters of straight line of single compressibility.

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Available abstract

It is shown that for 21 real substances the relation of Boyle temperature to the product of critical temperature and critical compressibility factor with high precision is equal to number 9, predicted by the state equation of van der Waals. We proposed the ratio for finding the critical volume through the relation of Boyle temperature to critical pressure. We also suggest a formula for determining the critical volume through the critical temperature and parameters of straight line of single compressibility.

Key concepts: Compressibility factor, Critical point (mathematics), Compressibility, Van der Waals equation, Thermodynamics, Reduced properties, Volume (thermodynamics), Equation of state

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