2014Unpublished venueRequires access

Transport and optical studies of PEO/PVP/LiClO 4 based polymer blend electrolytes

Karuppiah Kesavan, Chithra M. Mathew, C. Subbu, Swarna Lakshmi Rajendran

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Abstract

Fixed ratio of poly (ethylene oxide)/poly (vinyl pyrrolidone) (PEO /PVP) and various concentrations of lithium perchlorate (LiClO 4) were prepared by solvent casting technique. The m aximum ionic conductivity value was found to be 0.2307◊10 -5 Scm -1 for 8 wt% of LiClO 4 based system at ambient temperature. Three dimensional topographic image of the sample having a maximum ionic conductivity show small micropores which are responsible for the high ionic conductivi ty. The change in viscosity of the prepared samples were line with the ionic conductivity.

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Fixed ratio of poly (ethylene oxide)/poly (vinyl pyrrolidone) (PEO /PVP) and various concentrations of lithium perchlorate (LiClO 4) were prepared by solvent casting technique. The m aximum ionic conductivity value was found to be 0.2307◊10 -5 Scm -1 for 8 wt% of LiClO 4 based system at ambient temperature. Three dimensional topographic image of the sample having a maximum ionic conductivity show small micropores which are responsible for the high ionic conductivi ty. The change in viscosity of the prepared samples were line with the ionic conductivity.

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Available abstract

Fixed ratio of poly (ethylene oxide)/poly (vinyl pyrrolidone) (PEO /PVP) and various concentrations of lithium perchlorate (LiClO 4) were prepared by solvent casting technique. The m aximum ionic conductivity value was found to be 0.2307◊10 -5 Scm -1 for 8 wt% of LiClO 4 based system at ambient temperature. Three dimensional topographic image of the sample having a maximum ionic conductivity show small micropores which are responsible for the high ionic conductivi ty. The change in viscosity of the prepared samples were line with the ionic conductivity.

Key concepts: Lithium perchlorate, Ionic conductivity, Ethylene oxide, Electrolyte, Ionic bonding, Materials science, Conductivity, Viscosity

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