Reaction mechanisms: pericyclic reactions
Edyta M. Greer, Christopher V. Cosgriff
Abstract
Edyta M. Greer, Christopher V. Cosgriff
Abstract
This review summarizes a number of articles published in 2011 describing mechanisms of pericyclic reactions. The types of reactions studied were of the cycloaddition sort (e.g., [2+1], [2+2], [3+2], [4+2], etc.), as well as sigmatropic (e.g., [1,2], [1,3], [3,3] shifts, etc.), group transfer (e.g., ene), and electrocyclic types. Interestingly, the literature on pericyclic cascade reactions was quite rich in 2011.
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This review summarizes a number of articles published in 2011 describing mechanisms of pericyclic reactions. The types of reactions studied were of the cycloaddition sort (e.g., [2+1], [2+2], [3+2], [4+2], etc.), as well as sigmatropic (e.g., [1,2], [1,3], [3,3] shifts, etc.), group transfer (e.g., ene), and electrocyclic types. Interestingly, the literature on pericyclic cascade reactions was quite rich in 2011.
Key concepts: Pericyclic reaction, Sigmatropic reaction, sort, Cycloaddition, Chemistry, Computational chemistry, Stereochemistry, Computer science