Aromatic solvent induced shifts in molecules with and without a permanent electric dipole moment
Mansoor Ahmad, Lawrence R. Phillips
Abstract
Mansoor Ahmad, Lawrence R. Phillips
Abstract
It is shown that there is little justification for regarding aromatic solvent induced shifts as being of a ‘chemical’ origin. A literature method of determining the direction of molecular dipole moments is criticised. Data are presented for molecules which have no net dipole moment, and for some which do; the latter are analysed in terms of the approach of Laszlo and Engler.
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It is shown that there is little justification for regarding aromatic solvent induced shifts as being of a ‘chemical’ origin. A literature method of determining the direction of molecular dipole moments is criticised. Data are presented for molecules which have no net dipole moment, and for some which do; the latter are analysed in terms of the approach of Laszlo and Engler.
Key concepts: Dipole, Moment (physics), Bond dipole moment, Solvent, Electric dipole moment, Electric dipole transition, Chemistry, Molecule