1977Journal of the Chemical Society Perkin Transactions 2Requires access

Aromatic solvent induced shifts in molecules with and without a permanent electric dipole moment

Mansoor Ahmad, Lawrence R. Phillips

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Abstract

It is shown that there is little justification for regarding aromatic solvent induced shifts as being of a ‘chemical’ origin. A literature method of determining the direction of molecular dipole moments is criticised. Data are presented for molecules which have no net dipole moment, and for some which do; the latter are analysed in terms of the approach of Laszlo and Engler.

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It is shown that there is little justification for regarding aromatic solvent induced shifts as being of a ‘chemical’ origin. A literature method of determining the direction of molecular dipole moments is criticised. Data are presented for molecules which have no net dipole moment, and for some which do; the latter are analysed in terms of the approach of Laszlo and Engler.

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Available abstract

It is shown that there is little justification for regarding aromatic solvent induced shifts as being of a ‘chemical’ origin. A literature method of determining the direction of molecular dipole moments is criticised. Data are presented for molecules which have no net dipole moment, and for some which do; the latter are analysed in terms of the approach of Laszlo and Engler.

Key concepts: Dipole, Moment (physics), Bond dipole moment, Solvent, Electric dipole moment, Electric dipole transition, Chemistry, Molecule

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