Application of Iodide Ion Selective Electrode to the Study of Stepwise Formation Constant and Solubility Product of Lead Iodide
Wen‐Lie Chang, Fu‐Chung Chang, Shaw‐Chii Wu
Abstract
Wen‐Lie Chang, Fu‐Chung Chang, Shaw‐Chii Wu
Abstract
Abstract Iodide ion‐selective electrode were studied, prepared and applied for the complex formations and solubility product determination. The thermodynamic formation constant of PbI+ and the solubility product of PbI3 were found to be 54 and 9.2 × 10−9, respectively. The formation constant of PbNO3+ was calculated to be 4.6 from the different formation constant of PbI+ in perchlorate and nitrate media.
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Abstract Iodide ion‐selective electrode were studied, prepared and applied for the complex formations and solubility product determination. The thermodynamic formation constant of PbI+ and the solubility product of PbI3 were found to be 54 and 9.2 × 10−9, respectively. The formation constant of PbNO3+ was calculated to be 4.6 from the different formation constant of PbI+ in perchlorate and nitrate media.
Key concepts: Chemistry, Solubility equilibrium, Iodide, Solubility, Perchlorate, Stability constants of complexes, Inorganic chemistry, Electrode