Experimental and Theoretical Observations of Aromaticity in Heterocyclic XAl3− (X=Si, Ge, Sn, Pb) Systems
Xi Li, Haifeng Zhang, Lai‐Sheng Wang, Aleksey E. Kuznetsov, Nathan A. Cannon, Alexander I. Boldyrev
Abstract
Xi Li, Haifeng Zhang, Lai‐Sheng Wang, Aleksey E. Kuznetsov, Nathan A. Cannon, Alexander I. Boldyrev
Abstract
The concept of aromaticity is extended to a series of bimetallic heterocyclic species of general formula XAl3− (X = Si, Ge, Sn, Pb). The delocalization of the π electrons is important for the stability of the cyclic aromatic structure (see picture).
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The concept of aromaticity is extended to a series of bimetallic heterocyclic species of general formula XAl3− (X = Si, Ge, Sn, Pb). The delocalization of the π electrons is important for the stability of the cyclic aromatic structure (see picture).
Key concepts: Aromaticity, Electron delocalization, Bimetallic strip, Delocalized electron, Computational chemistry, Chemistry, Crystallography, Organic chemistry