On the bromination of 1,2,3‐triphenylazulene
Peter de Wit, Hans J. A. Lambrechts, Hans Cerfontain
Abstract
Peter de Wit, Hans J. A. Lambrechts, Hans Cerfontain
Abstract
Abstract The bromination of 1,2,3‐triphenylazulene (1) with a tenfold excess of bromine in CHCl3/CCl4 as solvent yields 5,7‐dibromo‐1,3‐bis(p‐bromophenyl)‐2‐phenylazulene and not a dibromo derivative as reported earlier1,2. With 1.0 equivalent of bromine or 2.0 equivalents of NBS, a mixture of the 5‐bromo and 5,7‐dibromo derivatives of 1 is obtained.
OpenAlex reports 3 citations for this work. Citation counts describe recorded attention and do not establish research quality.
A contribution statement is not available in the OpenAlex record.
Method details are not available in the OpenAlex metadata.
Findings are not separately available in the OpenAlex metadata.
Limitations are not available in the OpenAlex metadata.
Application details are not available in the OpenAlex metadata.
Abstract The bromination of 1,2,3‐triphenylazulene (1) with a tenfold excess of bromine in CHCl3/CCl4 as solvent yields 5,7‐dibromo‐1,3‐bis(p‐bromophenyl)‐2‐phenylazulene and not a dibromo derivative as reported earlier1,2. With 1.0 equivalent of bromine or 2.0 equivalents of NBS, a mixture of the 5‐bromo and 5,7‐dibromo derivatives of 1 is obtained.
Key concepts: Halogenation, Bromine, Derivative (finance), Chemistry, Solvent, Medicinal chemistry, Organic chemistry, Economics