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2004•Chemistry LettersRequires access

A Study on the Electronic Effect of Reactions of π-Allylpalladiums Using 2-Arylsulfonyloxy-3-chloropropenes with Ethyl Malonate and Their Synthetic Utilization

Kohei Gotoh, Yasutaka Matsuura, Fuminori Hatanaka, Setsuko Sato, Shinzoh Kagabu, Mitsuhiro Yoshimatsu

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Abstract

Abstract We have studied in detail the electronic effect on the reactions of π-allylpalladium with nucleophiles during the reactions of 2-arylsulfonyloxy-3-chloroprop-1-ene with diethyl malonate. The reaction rates increase increasing with the electron-withdrawing effects. We have also shown some synthetic utilization using these 2-arylsulfonyloxyprop-1-enes.

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Abstract We have studied in detail the electronic effect on the reactions of π-allylpalladium with nucleophiles during the reactions of 2-arylsulfonyloxy-3-chloroprop-1-ene with diethyl malonate. The reaction rates increase increasing with the electron-withdrawing effects. We have also shown some synthetic utilization using these 2-arylsulfonyloxyprop-1-enes.

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Available abstract

Abstract We have studied in detail the electronic effect on the reactions of π-allylpalladium with nucleophiles during the reactions of 2-arylsulfonyloxy-3-chloroprop-1-ene with diethyl malonate. The reaction rates increase increasing with the electron-withdrawing effects. We have also shown some synthetic utilization using these 2-arylsulfonyloxyprop-1-enes.

Key concepts: Chemistry, Diethyl malonate, Malonate, Nucleophile, Electronic effect, Organic chemistry, Medicinal chemistry, Catalysis

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A Study on the Electronic Effect of Reactions of π-Allylpalladiums Using 2-Arylsulfonyloxy-3-chloropropenes with Ethyl Malonate and Their Synthetic Utilization — Research Paper | ScholarLens