2014•Angewandte Chemie International EditionRequires access

Advancing into Water’s “No Man’s Land”: Two Liquid States?

Dietmar Paschek, Ralf Ludwig

Abstract

A tale of two liquids? Liquid water exhibits many anomalous properties which are strongly amplified in the supercooled state. A possible explanation for the unusual behavior is a phase transition between two distinct metastable forms of liquid water at deeply supercooled conditions. A recent theoretical study has confirmed the existence of this liquid-liquid phase transition.

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Key concepts: Supercooling, Metastability, Liquid water, Phase transition, Liquid liquid, Liquid phase, Chemical physics, Liquid state