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1996•Angewandte Chemie International Edition in EnglishRequires access

Metalated Tetra‐ and Penta(cyclopentadienyl)‐cyclopentadienyl Compounds: Syntheses by Multiple Pd‐Catalyzed Cyclopentadienylations

Roland Boese, Gabriele Bräunlich, Jean‐Pierre Gotteland, Jenn‐Tsang Hwang, Carsten Troll, K. Peter C. Vollhardt

Open publisher page 27 citations

Abstract

A one-step synthesis of the penta(cyclopentadienyl)cyclopentadienyl complex 1 can be achieved from [Mn(η5-C5I5)(CO)3] and CpSnMe3. Complex 1 can be converted to the corresponding novel pentaanion by reaction with BuLi. Because of their topography these compounds are interesting with regard to the construction of metalated semibuck-minsterfullerenes and metallobuckminsterfullerenes.

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What this paper is about

A one-step synthesis of the penta(cyclopentadienyl)cyclopentadienyl complex 1 can be achieved from [Mn(η5-C5I5)(CO)3] and CpSnMe3. Complex 1 can be converted to the corresponding novel pentaanion by reaction with BuLi. Because of their topography these compounds are interesting with regard to the construction of metalated semibuck-minsterfullerenes and metallobuckminsterfullerenes.

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Available abstract

A one-step synthesis of the penta(cyclopentadienyl)cyclopentadienyl complex 1 can be achieved from [Mn(η5-C5I5)(CO)3] and CpSnMe3. Complex 1 can be converted to the corresponding novel pentaanion by reaction with BuLi. Because of their topography these compounds are interesting with regard to the construction of metalated semibuck-minsterfullerenes and metallobuckminsterfullerenes.

Key concepts: Cyclopentadienyl complex, Tetra, Chemistry, Catalysis, Medicinal chemistry, Organic chemistry

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Metalated Tetra‐ and Penta(cyclopentadienyl)‐cyclopentadienyl Compounds: Syntheses by Multiple Pd‐Catalyzed Cyclopentadienylations — Research Paper | ScholarLens