2011•Dalton TransactionsRequires access
An uranyl citrate coordination polymer with a 3D open-framework involving uranyl cation-cation interactions
Jérôme Lhoste, Natacha Henry, Pascal Roussel, Thierry Loiseau, F. Abraham
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Abstract
A novel uranyl-organic compound incorporating citrate linker exhibits a 3D open-framework. It is built up from the connection of infinite chains of uranyl-centered polyhedra with citrate ligands, generating layers, which are further linked perpendicularly by isolated uranium tetranuclear motifs, involving uranyl cation-cation interactions.