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1961•Bulletin of the Chemical Society of JapanRequires access

Studies on Dehydroalanine Derivatives. V. Radical Polymerization of N-Carboxy-dehydroalanine Anhydride and of N-Phthaloyl-dehydroalanine. Synthesis of a New Amphoteric Polymer

Shumpei Sakakibara

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Abstract

Abstract Homopolymers of N-carboxy-dehydroalanine anhydride (I) and of N-phthaloyl-dehydroalanine (II), and copolymers of II with vinyl acetate were synthesized. Hydrolysis or hydrazinolysis was carried out to obtain polymers containing α-amino acid structures. Actual structures of these polymers were discussed.

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Abstract Homopolymers of N-carboxy-dehydroalanine anhydride (I) and of N-phthaloyl-dehydroalanine (II), and copolymers of II with vinyl acetate were synthesized. Hydrolysis or hydrazinolysis was carried out to obtain polymers containing α-amino acid structures. Actual structures of these polymers were discussed.

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Available abstract

Abstract Homopolymers of N-carboxy-dehydroalanine anhydride (I) and of N-phthaloyl-dehydroalanine (II), and copolymers of II with vinyl acetate were synthesized. Hydrolysis or hydrazinolysis was carried out to obtain polymers containing α-amino acid structures. Actual structures of these polymers were discussed.

Key concepts: Dehydroalanine, Chemistry, Hydrolysis, Polymer, Organic chemistry, Radical polymerization, Polymer chemistry, Vinyl acetate

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Studies on Dehydroalanine Derivatives. V. Radical Polymerization of N-Carboxy-dehydroalanine Anhydride and of N-Phthaloyl-dehydroalanine. Synthesis of a New Amphoteric Polymer — Research Paper | ScholarLens