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1970•Journal of the Chemical Society A Inorganic Physical TheoreticalRequires access

Vibrational and electronic spectra of transition-metal carbonyl complexes. Part VII. Infrared spectra of some cyclopentadienyl-metal carbonyl complexes

D.J. Parker, M. H. B. Stiddard

Open publisher page 35 citations

Abstract

The i.r. spectra of a number of π-cyclopentadienyl-metal carbonyl complexes have been studied in the range 4000–550 cm.–1 and with the aid of partially deuteriated derivatives of (π-C5H5)Mn(CO)3, [(π-C5H5)Mo(CO)3]2, and (π-C5H5)Mo(CO)2NO, it has been possible to assign satisfactorily vibrations of the cyclopentadienyl ring.

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The i.r. spectra of a number of π-cyclopentadienyl-metal carbonyl complexes have been studied in the range 4000–550 cm.–1 and with the aid of partially deuteriated derivatives of (π-C5H5)Mn(CO)3, [(π-C5H5)Mo(CO)3]2, and (π-C5H5)Mo(CO)2NO, it has been possible to assign satisfactorily vibrations of the cyclopentadienyl ring.

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Available abstract

The i.r. spectra of a number of π-cyclopentadienyl-metal carbonyl complexes have been studied in the range 4000–550 cm.–1 and with the aid of partially deuteriated derivatives of (π-C5H5)Mn(CO)3, [(π-C5H5)Mo(CO)3]2, and (π-C5H5)Mo(CO)2NO, it has been possible to assign satisfactorily vibrations of the cyclopentadienyl ring.

Key concepts: Cyclopentadienyl complex, Metal carbonyl, Chemistry, Transition metal, Infrared spectroscopy, Spectral line, Metal, Ring (chemistry)

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