2006ChemPhysChemRequires access

The Possibility of a Liquid Superconductor

Peter P. Edwards, C. N. R. Rao, Nikhil Kumar, A. S. Alexandrov

Open publisher page 26 citations

Abstract

All superconductors are solids in their superconducting state, this canonical electronic state of matter presently having only been observed well below the melting temperature of the solid. The discovery of high-temperature superconductivity in cuprates has widened significantly our horizons of the theoretical understanding of the physical phenomenon. A number of observations point to the possibility that superconductors with a high superconducting transition temperature may not be conventional Bardeen-Cooper-Schrieffer (BCS) superconductors, but rather derive from the Bose-Einstein condensation of real-space pairs. While BCS superconductors exist in the solid state (probably with the exception of metallic liquid hydrogen at ultrahigh pressures), we argue here that a superconducting charged Bose liquid may be found in a true liquid state of condensed matter at ambient pressure. An experimental scenario is outlined in fluid metal-ammonia solutions for stabilizing and observing a high-temperature superconducting liquid (ca. 230 K) or at least a vitreous superconductor in the corresponding quenched solutions (ca. 160 K).

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What this paper is about

All superconductors are solids in their superconducting state, this canonical electronic state of matter presently having only been observed well below the melting temperature of the solid. The discovery of high-temperature superconductivity in cuprates has widened significantly our horizons of the theoretical understanding of the physical phenomenon. A number of observations point to the possibility that superconductors with a high superconducting transition temperature may not be conventional Bardeen-Cooper-Schrieffer (BCS) superconductors, but rather derive from the Bose-Einstein condensation of real-space pairs. While BCS superconductors exist in the solid state (probably with the exception of metallic liquid hydrogen at ultrahigh pressures), we argue here that a superconducting charged Bose liquid may be found in a true liquid state of condensed matter at ambient pressure. An experimental scenario is outlined in fluid metal-ammonia solutions for stabilizing and observing a high-temperature superconducting liquid (ca. 230 K) or at least a vitreous superconductor in the corresponding quenched solutions (ca. 160 K).

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Available abstract

All superconductors are solids in their superconducting state, this canonical electronic state of matter presently having only been observed well below the melting temperature of the solid. The discovery of high-temperature superconductivity in cuprates has widened significantly our horizons of the theoretical understanding of the physical phenomenon. A number of observations point to the possibility that superconductors with a high superconducting transition temperature may not be conventional Bardeen-Cooper-Schrieffer (BCS) superconductors, but rather derive from the Bose-Einstein condensation of real-space pairs. While BCS superconductors exist in the solid state (probably with the exception of metallic liquid hydrogen at ultrahigh pressures), we argue here that a superconducting charged Bose liquid may be found in a true liquid state of condensed matter at ambient pressure. An experimental scenario is outlined in fluid metal-ammonia solutions for stabilizing and observing a high-temperature superconducting liquid (ca. 230 K) or at least a vitreous superconductor in the corresponding quenched solutions (ca. 160 K).

Key concepts: Superconductivity, Condensed matter physics, State of matter, Cuprate, Room-temperature superconductor, High-temperature superconductivity, Metallic hydrogen, Physics

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