Solvent-dependent chiral assembling of two zinc porphyrins in a zinc–free-base–zinc trimeric porphyrin array
Toru Arai, Kiyoshi Takei, Norikazu Nishino, Tsutomu Fujimoto
Abstract
Toru Arai, Kiyoshi Takei, Norikazu Nishino, Tsutomu Fujimoto
Abstract
A pair of zinc porphyrins attached to a free-base porphyrin shows a strong split Cotton effect in CH2Cl2, in which the leucine esters on the rims lead to chiral assembly.
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A pair of zinc porphyrins attached to a free-base porphyrin shows a strong split Cotton effect in CH2Cl2, in which the leucine esters on the rims lead to chiral assembly.
Key concepts: Porphyrin, Zinc, Free base, Chemistry, Solvent, Base (topology), Polymer chemistry, Photochemistry