Ik‐Hwan Um, Young‐Min Park, Erwin Buncel
Abstract
The increasing α-effect observed in MeCN–H2O solvent mixtures, which contrasts with the previously found bell-shaped dependence on solvent composition in the DMSO–H2O system, is attributed to the differential solvent effect on basicities of the α- and normal nucleophiles in the former case.
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The increasing α-effect observed in MeCN–H2O solvent mixtures, which contrasts with the previously found bell-shaped dependence on solvent composition in the DMSO–H2O system, is attributed to the differential solvent effect on basicities of the α- and normal nucleophiles in the former case.
Key concepts: Solvent, Nucleophile, Solvent effects, Chemistry, Solvent exposure, Composition (language), Computational chemistry, Organic chemistry