2006•Chemical CommunicationsRequires access
A key step in the formation of acrylic acid from CO 2 and ethylene: the transformation of a nickelalactone into a nickel-acrylate complex
Reinald Fischer, Jens Langer, A. Malassa, Dirk Walther, Helmar Görls, G. Vaughan
Open publisher page 136 citations
Abstract
The reaction of a nickelalactone with dppm, resulting in the formation of a stable binuclear Ni(I) complex with an acrylate, a Ph2P- and a dppm bridge, models a key step in the formation of acrylic acid from CO2 and ethylene.