2012Journal of Hydrogen and New EnergyOpen access

Effects of Nafion Contents on the Performance of MEAs Prepared by Decal-Transfer Method

Gyeong-Hee Kim, Eunae Cho, Jonghee Han, Sunghyun Kim, KwangSup Eom

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Abstract

Nafion ionomer located in electrode helps to increase the platinum utilization and proton conductivity. To achieve higher performance in PEMFCs, it is important an optimum Nafion content in the electrode. As the platinum loading and fabricated method depend on the optimum Nafion content. In this study, we have examined the interrelationship between platinum loading and Nafion content fabricated by decal transfer method. For electrodes with 0.25 and 0.4 mg/ $cm^2$ Pt loading, best performance was obtained at 25 wt.% Nafion ionomer loading. It is also found that MEA with 0.25 mg/ $cm^2$ Pt, the optimum Nafion content appears differently at low and high current density.

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Nafion ionomer located in electrode helps to increase the platinum utilization and proton conductivity. To achieve higher performance in PEMFCs, it is important an optimum Nafion content in the electrode. As the platinum loading and fabricated method depend on the optimum Nafion content. In this study, we have examined the interrelationship between platinum loading and Nafion content fabricated by decal transfer method. For electrodes with 0.25 and 0.4 mg/ $cm^2$ Pt loading, best performance was obtained at 25 wt.% Nafion ionomer loading. It is also found that MEA with 0.25 mg/ $cm^2$ Pt, the optimum Nafion content appears differently at low and high current density.

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Available abstract

Nafion ionomer located in electrode helps to increase the platinum utilization and proton conductivity. To achieve higher performance in PEMFCs, it is important an optimum Nafion content in the electrode. As the platinum loading and fabricated method depend on the optimum Nafion content. In this study, we have examined the interrelationship between platinum loading and Nafion content fabricated by decal transfer method. For electrodes with 0.25 and 0.4 mg/ $cm^2$ Pt loading, best performance was obtained at 25 wt.% Nafion ionomer loading. It is also found that MEA with 0.25 mg/ $cm^2$ Pt, the optimum Nafion content appears differently at low and high current density.

Key concepts: Nafion, Ionomer, Platinum, Materials science, Electrode, Conductivity, Composite material, Chemical engineering

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