133Cs NMR investigation of 2D frustrated Heisenberg antiferromagnet, Cs2CuCl4

We report 133 Cs nuclear magnetic resonance (NMR) measurements on the 2D frustrated Heisenberg antiferromagnet Cs 2 CuCl 4 down to 2 K and up to 15 T. We show that 133 Cs NMR is a good probe of the magnetic degrees of freedom in this material. Cu spin degrees of freedom are sensed through a strong anisotropic hyperfine coupling. The spin excitation gap opens above the critical saturation field. The gap value was determined from the activation energy of the nuclear spin-lattice relaxation rate in a magnetic field applied parallel to the Cu chains ( axis). The values of the g -factor and the saturation field are consistent with the neutron-scattering and magnetization results. The measurements of the spin–spin relaxation time are exploited to show that no structural changes occur down to the lowest temperatures investigated.