1970•Journal of the Chemical Society A Inorganic Physical TheoreticalRequires access
Reactions between phosphorus pentafluoride and methylamine, ethylamine, and t-butylamine
John S. Harman, David W. A. Sharp
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Abstract
The reactions between phosphorus pentafluoride and monoalkylamines are complex and yield adducts, alkylammonium hexafluorophosphates, alkylaminotetrafluorophosphoranes, and bis(alkylamino)trifluorophosphoranes under the appropriate conditions. A possible sequence of reactions is discussed.