Unusual anti-selective asymmetric conjugate addition of aldehydes to nitroalkenes catalyzed by a biphenyl-based chiral secondary amine
Taichi Kano, Hisashi Sugimoto, Osamu Tokuda, Keiji Maruoka
Abstract
Taichi Kano, Hisashi Sugimoto, Osamu Tokuda, Keiji Maruoka
Abstract
Unusual anti-selectivity was observed in the conjugate addition of aldehydes to nitroalkenes, when a biphenyl-based chiral secondary amine was used as catalyst.
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Unusual anti-selectivity was observed in the conjugate addition of aldehydes to nitroalkenes, when a biphenyl-based chiral secondary amine was used as catalyst.
Key concepts: Conjugate, Amine gas treating, Biphenyl, Catalysis, Chemistry, Selectivity, Combinatorial chemistry, Organic chemistry