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2012•CrystEngCommRequires access

Direct observation of conformational change of adipate dianions encapsulated in water clusters

Geng‐Geng Luo, Dongliang L. Wu, Jihuai Wu, Jiu-Xu Xia, Li Liu, Jing‐Cao Dai

Open publisher page 22 citations

Abstract

Two novel hydrated adipate dianions including (adip)aaa·(H2O)16 and (adip)gag·(H2O)20 (adip = dianion of adipic acid, aaa = anti–anti–anti and gag = gauche–anti–gauche) were observed in two silver-based cationic hosts. They not only reveal the precise arrangement of water clusters around the carboxylate groups and aliphatic chains of adipate dianions, but show the conformational change of adipate dianions in water clusters, for the first time.

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What this paper is about

Two novel hydrated adipate dianions including (adip)aaa·(H2O)16 and (adip)gag·(H2O)20 (adip = dianion of adipic acid, aaa = anti–anti–anti and gag = gauche–anti–gauche) were observed in two silver-based cationic hosts. They not only reveal the precise arrangement of water clusters around the carboxylate groups and aliphatic chains of adipate dianions, but show the conformational change of adipate dianions in water clusters, for the first time.

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OpenAlex reports 22 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

Two novel hydrated adipate dianions including (adip)aaa·(H2O)16 and (adip)gag·(H2O)20 (adip = dianion of adipic acid, aaa = anti–anti–anti and gag = gauche–anti–gauche) were observed in two silver-based cationic hosts. They not only reveal the precise arrangement of water clusters around the carboxylate groups and aliphatic chains of adipate dianions, but show the conformational change of adipate dianions in water clusters, for the first time.

Key concepts: Adipate, Carboxylate, Cationic polymerization, Adipic acid, Chemistry, Conformational change, Polymer chemistry, Crystallography

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