1971Journal of the Chemical Society B Physical OrganicRequires access

Deviations in the electronic absorption spectra of di- and tri-arylmethane dyes

Roshan Castelino, Geoffrey Hallas

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Abstract

The first-frequency absorption bands of electronically unsymmetrical derivatives of Michler's Hydrol Blue show bathochromic deviations, in contrast to the behaviour of these bands in the spectra of related cyanine dyes. The first bands of analogous derivatives of Malachite Green may show either bathochromic or hypsochromic deviations.

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The first-frequency absorption bands of electronically unsymmetrical derivatives of Michler's Hydrol Blue show bathochromic deviations, in contrast to the behaviour of these bands in the spectra of related cyanine dyes. The first bands of analogous derivatives of Malachite Green may show either bathochromic or hypsochromic deviations.

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Available abstract

The first-frequency absorption bands of electronically unsymmetrical derivatives of Michler's Hydrol Blue show bathochromic deviations, in contrast to the behaviour of these bands in the spectra of related cyanine dyes. The first bands of analogous derivatives of Malachite Green may show either bathochromic or hypsochromic deviations.

Key concepts: Bathochromic shift, Hypsochromic shift, Cyanine, Chemistry, Malachite green, Absorption spectroscopy, Spectral line, Photochemistry

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