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Chemistry and clay mineralogy of Thai Natraqualfs.

C. Kaewmano, Irb Kheoruenromne, A. Suddhiprakarn, R. J. Gilkes

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Abstract

Thai Natraqualfs including saline7sodic and sodic soils from eight sites on alluvium or wash over residuum derived from clastic sedimentary rock under a tropical savanna climate were investigated. They have a large variation in EC values ranging from 0.3 7 60.5 dS/m with variable ESP values ranging from 0.1731.5% and SAR values < 13. Kaolinite is the dominant mineral in the clay fraction with small amounts of smectite and a trace of illite. Transmission electron microscope (TEM) micrographs of kaolinite show a variety of crystal morphologies including euhedral, subhedral and anhedral platy crystals. Anhedral crystals are abundant in saline7sodic soils and a high proportion of euhedral crystals occur in sodic soils. The median size of kaolinite crystal ranges from 43769 nm. Morphology and size of kaolinite crystals for these Natraqualfs are statistically related to electrical conductivity and soil pH. Decreasing kaolinite crystal size is associated with increasing soil salinity and exchangeable Na.

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Thai Natraqualfs including saline7sodic and sodic soils from eight sites on alluvium or wash over residuum derived from clastic sedimentary rock under a tropical savanna climate were investigated. They have a large variation in EC values ranging from 0.3 7 60.5 dS/m with variable ESP values ranging from 0.1731.5% and SAR values < 13. Kaolinite is the dominant mineral in the clay fraction with small amounts of smectite and a trace of illite. Transmission electron microscope (TEM) micrographs of kaolinite show a variety of crystal morphologies including euhedral, subhedral and anhedral platy crystals. Anhedral crystals are abundant in saline7sodic soils and a high proportion of euhedral crystals occur in sodic soils. The median size of kaolinite crystal ranges from 43769 nm. Morphology and size of kaolinite crystals for these Natraqualfs are statistically related to electrical conductivity and soil pH. Decreasing kaolinite crystal size is associated with increasing soil salinity and exchangeable Na.

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Available abstract

Thai Natraqualfs including saline7sodic and sodic soils from eight sites on alluvium or wash over residuum derived from clastic sedimentary rock under a tropical savanna climate were investigated. They have a large variation in EC values ranging from 0.3 7 60.5 dS/m with variable ESP values ranging from 0.1731.5% and SAR values < 13. Kaolinite is the dominant mineral in the clay fraction with small amounts of smectite and a trace of illite. Transmission electron microscope (TEM) micrographs of kaolinite show a variety of crystal morphologies including euhedral, subhedral and anhedral platy crystals. Anhedral crystals are abundant in saline7sodic soils and a high proportion of euhedral crystals occur in sodic soils. The median size of kaolinite crystal ranges from 43769 nm. Morphology and size of kaolinite crystals for these Natraqualfs are statistically related to electrical conductivity and soil pH. Decreasing kaolinite crystal size is associated with increasing soil salinity and exchangeable Na.

Key concepts: Kaolinite, Illite, Platy, Clay minerals, Mineralogy, Vertisol, Soil water, Clastic rock

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