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2001•Journal of the Chemical Society Dalton TransactionsRequires access

Geometrical preferences of complexes of terpyridine N-oxide ligands: synthesis and crystal structures of nickel(II) with terpyridine 1,1′,1″-trioxide, terpyridine 1,1″-dioxide and terpyridine 1-oxide

Angelo J. Amoroso, Miles W. Burrows, Anthony A. Dickinson, Cameron J. Jones, David J. Willock, Wing‐Tak Wong

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Abstract

[NiL2][ClO4]2 complexes (L = terpyridine 1,1′,1″-trioxide, terpyridine 1,1″-dioxide and terpyridine 1-oxide) have been prepared and crystallographically characterised; data shows a predictable variation in ligand conformation, such as facial or meridonal binding, which is in agreement with DFT calculations.

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What this paper is about

[NiL2][ClO4]2 complexes (L = terpyridine 1,1′,1″-trioxide, terpyridine 1,1″-dioxide and terpyridine 1-oxide) have been prepared and crystallographically characterised; data shows a predictable variation in ligand conformation, such as facial or meridonal binding, which is in agreement with DFT calculations.

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Available abstract

[NiL2][ClO4]2 complexes (L = terpyridine 1,1′,1″-trioxide, terpyridine 1,1″-dioxide and terpyridine 1-oxide) have been prepared and crystallographically characterised; data shows a predictable variation in ligand conformation, such as facial or meridonal binding, which is in agreement with DFT calculations.

Key concepts: Terpyridine, Chemistry, Trioxide, Oxide, Nickel, Ligand (biochemistry), Inorganic chemistry, Polymer chemistry

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Geometrical preferences of complexes of terpyridine N-oxide ligands: synthesis and crystal structures of nickel(II) with terpyridine 1,1′,1″-trioxide, terpyridine 1,1″-dioxide and terpyridine 1-oxide — Research Paper | ScholarLens