2000•Analytical LettersRequires access

Silver-Selective Electrode Based on a Direct Modified Electrode Silver Hexacyanoferrate(II) Film

Ali Eftekhari

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Abstract

A silver hexacyanoferrate(II) modified electrode is introduced as a silver-selective electrode. The electrode was prepared based on a new type of chemically modified electrodes by direct modification of the electrode surface. The electrode response characteristics were investigated by potentiometry. The calibration curve of the electrode shows a linear potentiometric response to Ag+ in the range of 10-7 - 10-2 M with detection limit of 5 × 10-8. The modified electrode described in this paper is very simple, low cost and has linear response to Ag+ with a slope of 52-55 mV per decade.

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What this paper is about

A silver hexacyanoferrate(II) modified electrode is introduced as a silver-selective electrode. The electrode was prepared based on a new type of chemically modified electrodes by direct modification of the electrode surface. The electrode response characteristics were investigated by potentiometry. The calibration curve of the electrode shows a linear potentiometric response to Ag+ in the range of 10-7 - 10-2 M with detection limit of 5 × 10-8. The modified electrode described in this paper is very simple, low cost and has linear response to Ag+ with a slope of 52-55 mV per decade.

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Available abstract

A silver hexacyanoferrate(II) modified electrode is introduced as a silver-selective electrode. The electrode was prepared based on a new type of chemically modified electrodes by direct modification of the electrode surface. The electrode response characteristics were investigated by potentiometry. The calibration curve of the electrode shows a linear potentiometric response to Ag+ in the range of 10-7 - 10-2 M with detection limit of 5 × 10-8. The modified electrode described in this paper is very simple, low cost and has linear response to Ag+ with a slope of 52-55 mV per decade.

Key concepts: Electrode, Palladium-hydrogen electrode, Quinhydrone electrode, Chemistry, Potentiometric titration, Standard hydrogen electrode, Reference electrode, Absolute electrode potential

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