Three important calorimetric applications of a classic thermodynamic equation
Michael J. Blandamer, Paul M. Cullis, Peter T. Gleeson
Abstract
Michael J. Blandamer, Paul M. Cullis, Peter T. Gleeson
Abstract
The thermodynamic background to three calorimetric techniques is discussed; (i) titration microcalorimetry, (ii) adiabatic calorimetry, and (iii) heat conduction calorimetry. Relevant equations for each technique are derived from a common equation for the enthalpy H of a closed system. General patterns which emerge in the measured parameters are presented for adiabatic and heat conduction calorimeters linked to applications of these techniques.
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The thermodynamic background to three calorimetric techniques is discussed; (i) titration microcalorimetry, (ii) adiabatic calorimetry, and (iii) heat conduction calorimetry. Relevant equations for each technique are derived from a common equation for the enthalpy H of a closed system. General patterns which emerge in the measured parameters are presented for adiabatic and heat conduction calorimeters linked to applications of these techniques.
Key concepts: Isothermal microcalorimetry, Calorimetry, Adiabatic process, Enthalpy, Thermodynamics, Thermal conduction, Isothermal titration calorimetry, Calorimeter (particle physics)