ChemInform Abstract: Thorium(IV)—Selenate Clusters Containing an Octanuclear Th(IV) Hydroxide/Oxide Core.
Karah E. Knope, Monica Vasiliu, David A. Dixon, L. Soderholm
Abstract
Karah E. Knope, Monica Vasiliu, David A. Dixon, L. Soderholm
Abstract
Abstract [Th8(μ3‐O)4 (μ2‐OH)8(H2O)15 (SeO4)8]·7.5H2O (I) and [Th8(O)4(OH)8(H2O)17 (SeO4)8]·nH2O (II) are obtained from an aqueous slurry of Th(NO3)4, NH4OH, and H2SeO4 (boiling on a hot plate for about 10 min).
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Abstract [Th8(μ3‐O)4 (μ2‐OH)8(H2O)15 (SeO4)8]·7.5H2O (I) and [Th8(O)4(OH)8(H2O)17 (SeO4)8]·nH2O (II) are obtained from an aqueous slurry of Th(NO3)4, NH4OH, and H2SeO4 (boiling on a hot plate for about 10 min).
Key concepts: Chemistry, Aqueous solution, Hydroxide, Thorium, Oxide, Slurry, Selenate, Nuclear chemistry