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1970•Transactions of the Faraday SocietyRequires access

Pulse radiolytic induced transient electrical conductance in liquid solutions. Part 1.—Technique and the radiolysis of water

G.C. Barker, P. Fowles, D. C. Sammon, Bradley D. Stringer

Open publisher page 67 citations

Abstract

A sensitive technique is described for the study of transient ionic intermediates produced in the radiolysis of liquid solutions. Results are given for the radiolysis of water in the pH range 4-10. Rate constants for e–aq+ H3O+ and OH–+ H3O+ are in good agreement with values obtained by other methods. Activation energies have been measured for both reactions and for the diffusion of the hydrated electron.

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What this paper is about

A sensitive technique is described for the study of transient ionic intermediates produced in the radiolysis of liquid solutions. Results are given for the radiolysis of water in the pH range 4-10. Rate constants for e–aq+ H3O+ and OH–+ H3O+ are in good agreement with values obtained by other methods. Activation energies have been measured for both reactions and for the diffusion of the hydrated electron.

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Available abstract

A sensitive technique is described for the study of transient ionic intermediates produced in the radiolysis of liquid solutions. Results are given for the radiolysis of water in the pH range 4-10. Rate constants for e–aq+ H3O+ and OH–+ H3O+ are in good agreement with values obtained by other methods. Activation energies have been measured for both reactions and for the diffusion of the hydrated electron.

Key concepts: Radiolysis, Chemistry, Solvated electron, Diffusion, Reaction rate constant, Conductance, Ionic bonding, Transient (computer programming)

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Pulse radiolytic induced transient electrical conductance in liquid solutions. Part 1.—Technique and the radiolysis of water — Research Paper | ScholarLens