Vinylhydroquinone. V. Tri‐n‐butylborane‐initiated copolymerization of maleic anhydride and redox property of copolymers
Susumu Iwabuchi, Yasaku Watanabe, Takayuki Nakahira, Kuniharau Kojima
Abstract
Susumu Iwabuchi, Yasaku Watanabe, Takayuki Nakahira, Kuniharau Kojima
Abstract
Abstract Tri‐n‐butylborane (TBB) was found to be capable of initiating the copolymerization of vinylhydroquinone (VHQ) with maleic anhydride (MAn) and diethyl fumarate (DEF) in cyclohexanone at 30°C under nitrogen. Redox potentials of the VHQ–MAn copolymer obtained were examined. These results, along with spectroscopic data, indicate that the copolymers are of a highly alternating character.
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Abstract Tri‐n‐butylborane (TBB) was found to be capable of initiating the copolymerization of vinylhydroquinone (VHQ) with maleic anhydride (MAn) and diethyl fumarate (DEF) in cyclohexanone at 30°C under nitrogen. Redox potentials of the VHQ–MAn copolymer obtained were examined. These results, along with spectroscopic data, indicate that the copolymers are of a highly alternating character.
Key concepts: Copolymer, Maleic anhydride, Polymer chemistry, Cyclohexanone, Redox, Chemistry, Materials science, Organic chemistry