1979Journal of Polymer Science Polymer Chemistry EditionRequires access

Vinylhydroquinone. V. Tri‐n‐butylborane‐initiated copolymerization of maleic anhydride and redox property of copolymers

Susumu Iwabuchi, Yasaku Watanabe, Takayuki Nakahira, Kuniharau Kojima

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Abstract

Abstract Tri‐n‐butylborane (TBB) was found to be capable of initiating the copolymerization of vinylhydroquinone (VHQ) with maleic anhydride (MAn) and diethyl fumarate (DEF) in cyclohexanone at 30°C under nitrogen. Redox potentials of the VHQ–MAn copolymer obtained were examined. These results, along with spectroscopic data, indicate that the copolymers are of a highly alternating character.

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Abstract Tri‐n‐butylborane (TBB) was found to be capable of initiating the copolymerization of vinylhydroquinone (VHQ) with maleic anhydride (MAn) and diethyl fumarate (DEF) in cyclohexanone at 30°C under nitrogen. Redox potentials of the VHQ–MAn copolymer obtained were examined. These results, along with spectroscopic data, indicate that the copolymers are of a highly alternating character.

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Available abstract

Abstract Tri‐n‐butylborane (TBB) was found to be capable of initiating the copolymerization of vinylhydroquinone (VHQ) with maleic anhydride (MAn) and diethyl fumarate (DEF) in cyclohexanone at 30°C under nitrogen. Redox potentials of the VHQ–MAn copolymer obtained were examined. These results, along with spectroscopic data, indicate that the copolymers are of a highly alternating character.

Key concepts: Copolymer, Maleic anhydride, Polymer chemistry, Cyclohexanone, Redox, Chemistry, Materials science, Organic chemistry

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