The nature of chalcopyrite inclusions in sphalerite; exsolution, coprecipitation, or "disease"?
Н. С. Бортников, A. D. Genkin, M. G. Dobrovol’skaya, G. N. Muravitskaya, А. А. Филимонова
Abstract
Н. С. Бортников, A. D. Genkin, M. G. Dobrovol’skaya, G. N. Muravitskaya, А. А. Филимонова
Abstract
Chalcopyrite inclusions in sphalerite, once considered to be only exsolution poducts, have been suggested to be replacements of Fe-rich sphalerite. This study reveals that (1) chalcopyrite inclusions were found in sphalerite with different iron contents: both Fe-poor varieties from 0.5 to 2 wt percent and Fe-rich, from 8 to 14 wt percent; (2) chalcopyrite inclusions were produced by replacement as the result of interaction of sphalerite with solutions, which transported both copper and iron; and (3) coprecipitation of sphalerite and chalcopyrite is an alternative mechanism of formation of the chalcopyrite inclusions in the ore deposits studied.
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Chalcopyrite inclusions in sphalerite, once considered to be only exsolution poducts, have been suggested to be replacements of Fe-rich sphalerite. This study reveals that (1) chalcopyrite inclusions were found in sphalerite with different iron contents: both Fe-poor varieties from 0.5 to 2 wt percent and Fe-rich, from 8 to 14 wt percent; (2) chalcopyrite inclusions were produced by replacement as the result of interaction of sphalerite with solutions, which transported both copper and iron; and (3) coprecipitation of sphalerite and chalcopyrite is an alternative mechanism of formation of the chalcopyrite inclusions in the ore deposits studied.
Key concepts: Sphalerite, Chalcopyrite, Geology, Coprecipitation, Geochemistry, Copper, Pyrite, Mineralogy