Improving Accuracy in the Determination of Aromatics in Gasoline by Gas Chromatography--Mass Spectrometry
Mette Mathiesen, A. J. Lubeck
Abstract
Mette Mathiesen, A. J. Lubeck
Abstract
Petroleum industry studies show that the total aromatics content of a gasoline as determined by ASTM Standard Test Method D5769, “Determination of Benzene, Toluene, and Total Aromatics in Finished Gasoline by Gas Chromatography/Mass Spectrometry”, is consistently lower than results obtained using other standard test methods. Sources of this bias are investigated, and practical modifications to D5769 to reduce the bias are proposed.
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Petroleum industry studies show that the total aromatics content of a gasoline as determined by ASTM Standard Test Method D5769, “Determination of Benzene, Toluene, and Total Aromatics in Finished Gasoline by Gas Chromatography/Mass Spectrometry”, is consistently lower than results obtained using other standard test methods. Sources of this bias are investigated, and practical modifications to D5769 to reduce the bias are proposed.
Key concepts: Chemistry, Gasoline, Toluene, Mass spectrometry, Chromatography, Gas chromatography, Benzene, Gas chromatography–mass spectrometry