2004•Angewandte Chemie International EditionRequires access

New Clathrate Hydrate Structure: High‐Pressure Tetrahydrofuran Hydrate with One Type of Cavity

Alexander Kurnosov, Vladislav Yu. Komarov, В. И. Воронин, А. Е. Teplykh, Andrej Yu. Manakov

Abstract

Water cages: A water framework consisting of uniform space-filling polyhedral cages containing tetrahydrofuran molecules has been detected in a new clathrate hydrate formed under a pressure of 0.8 GPa. Topologically the cage represents a space-filling tetradecahedron with four tetra-, four penta-, and six hexagonal faces (see picture).

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Key concepts: Tetrahydrofuran, Clathrate hydrate, Hydrate, Crystallography, Materials science, Hexagonal crystal system, Molecule, Space (punctuation)