1995•Journal of Materials ChemistryRequires access

Semi-conducting Langmuir–Blodgett films of a novel amphiphilic bis(tetrathiafulvalene) derivative

Leonid M. Goldenberg, Vladimir Yu. Khodorkovsky, James Y. Becker, Martin R. Bryce, Michael C. Petty

Abstract

Amphiphilic bis(tetrathiafulvalene) derivative 1 has been synthesized and assembled into Langmuir-Blodgett multilayers which, upon doping with iodine, afford stable semiconducting thin films of a mixed-valence salt, with in-plane roomtemperature conductivity, σrt= 10–3σ cm–1.

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Key concepts: Tetrathiafulvalene, Langmuir–Blodgett film, Amphiphile, Conductivity, Derivative (finance), Doping, Materials science, Valence (chemistry)