1999•Journal of the Chemical Society Dalton TransactionsRequires access

Procedure for the determination of redox potentials of chemically (and electrochemically) irreversible inorganic redox couples from spectroscopic data

Francisco Sánchez, Pilar Pérez, Francisco Pérez, Manuel López‐López

Abstract

A procedure for the estimation of the redox potentials of chemically (or electrochemically) irreversible couples based on optical measurements and on the Marcus and Hush equations has been proposed and tested through the determination of redox potentials of different Co(NH3)5L3+/2+ redox couples. The results are in agreement with the expectations based on the reactivity of these complexes.

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Key concepts: Redox, Reactivity (psychology), Chemistry, Electrochemistry, Half-reaction, Oxidation reduction, Inorganic chemistry, Physical chemistry