ScholarLens Back to search
1981•Bulletin des Sociétés Chimiques BelgesRequires access

Extraction and Spectrophotometric Determination of Zirconium with N‐P‐Chlorophenylbenzohydroxamic Acid and Morin

Yadvendra Kumar Agrawal, Satish A Patel

Open publisher page 2 citations

Abstract

Abstract A spectrophotometric and a fluorimetric method for the determination of zirconium with N‐p‐chlorophenylbenzohydroxamic acid and morin have been developed. The procedure is based on the extraction of zirconium with N‐p‐Cl‐BHA into iso‐amyl alcohol from 0.2‐0.5 N H2SO4 and then forming its complex with morin. The greenish yellow complex has a maximum absorbance at 420 nm with a molar absorptivity 3.5×104 1 mol−1 cm−1 and gives the fluorescence. The intensity of the Zr‐p‐Cl‐BHA‐morin complex can be enhanced by the addition of ammonium carbonate and the molar absorptivity becomes 1.3×105 1 mol−1 cm−1 at 410 nm.

About this research paper

What this paper is about

Abstract A spectrophotometric and a fluorimetric method for the determination of zirconium with N‐p‐chlorophenylbenzohydroxamic acid and morin have been developed. The procedure is based on the extraction of zirconium with N‐p‐Cl‐BHA into iso‐amyl alcohol from 0.2‐0.5 N H2SO4 and then forming its complex with morin. The greenish yellow complex has a maximum absorbance at 420 nm with a molar absorptivity 3.5×104 1 mol−1 cm−1 and gives the fluorescence. The intensity of the Zr‐p‐Cl‐BHA‐morin complex can be enhanced by the addition of ammonium carbonate and the molar absorptivity becomes 1.3×105 1 mol−1 cm−1 at 410 nm.

Why it matters

OpenAlex reports 2 citations for this work. Citation counts describe recorded attention and do not establish research quality.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

Abstract A spectrophotometric and a fluorimetric method for the determination of zirconium with N‐p‐chlorophenylbenzohydroxamic acid and morin have been developed. The procedure is based on the extraction of zirconium with N‐p‐Cl‐BHA into iso‐amyl alcohol from 0.2‐0.5 N H2SO4 and then forming its complex with morin. The greenish yellow complex has a maximum absorbance at 420 nm with a molar absorptivity 3.5×104 1 mol−1 cm−1 and gives the fluorescence. The intensity of the Zr‐p‐Cl‐BHA‐morin complex can be enhanced by the addition of ammonium carbonate and the molar absorptivity becomes 1.3×105 1 mol−1 cm−1 at 410 nm.

Key concepts: Morin, Molar absorptivity, Zirconium, Absorbance, Chemistry, Nuclear chemistry, Extraction (chemistry), Fluorescence

Related papers

Related paper 1Related paper 2Related paper 3
Back to paper searchBrowse research topicsOriginal source
Extraction and Spectrophotometric Determination of Zirconium with N‐P‐Chlorophenylbenzohydroxamic Acid and Morin — Research Paper | ScholarLens