The Theory of Pericyclic Reactions
Nicoloas D. Epiotis
Abstract
Nicoloas D. Epiotis
Abstract
Abstract Pericyclic reactions include thermal and photochemical cycloadditions and cycloreversions, electrocyclic reactions and sigmatropic shifts. Configuration interaction analysis can be used for making predictions about preferred reaction pathways, about reaction rates, about the nature of possible intermediate steps, and above all about the stereochemistry of such reactions.
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Abstract Pericyclic reactions include thermal and photochemical cycloadditions and cycloreversions, electrocyclic reactions and sigmatropic shifts. Configuration interaction analysis can be used for making predictions about preferred reaction pathways, about reaction rates, about the nature of possible intermediate steps, and above all about the stereochemistry of such reactions.
Key concepts: Pericyclic reaction, Sigmatropic reaction, Computational chemistry, Chemistry, Electrocyclic reaction, Photochemistry, Stereochemistry, Bicyclic molecule